I am using Bitdefender Total Security 2018 and I can't get the firewall rules to work for my Synology NAS. I added the NAS IP to the network exceptions as demonstrated here: https://www.bitdefender.com/consumer/support/answer/2397/
Unfortunately, when I select the NAS in the Windows 10 network explorer I get the error that it couldn't be accessed. When turning the Bitdefender Firewall off then everything works ok.
Do you have another tip what I can try?